交叉偶联反应（cross-coupling reaction）是有机化学领域中的一种重要合成方法，通过将两种不同的有机分子中的功能团（通常是碳-碳键）进行连接，从而形成新的分子结构。这一反应广泛应用于药物合成、材料科学和农业化学等领域，被公认为是现代有机合成化学的关键技术之一。 例句1: The cross-coupling reaction between aryl halides and alkenes is commonly used for the synthesis of biaryl compounds. 例句2: Palladium-catalyzed cross-coupling reaction has revolutionized the field of organic synthesis by enabling the construction of complex molecular architectures in a predictable and efficient manner.
交叉偶联反应,cross-coupling reaction
1)cross-coupling reaction交叉偶联反应
1.Palladium-catalyzedcross-coupling reactions is one of the most important methods for constructing the C—C bonds in organic synthesis.钯催化的交叉偶联反应已经成为有机合成化学中构建C—C键最重要的方法之一 。
2.Thecross-coupling reaction has recently become one of research focuses in organic synthetic chemistry.交叉偶联反应是目前有机合成化学研究的热点之一。
3.Based on the reactivityes difference of tributylstannyl and sulfonyl groups, we carried out thecross-coupling reaction of (E)-α-stannyl.利用(E)-α-锡基烯基砜分子中锡基团和砜基团的性质差别,研究了在钯络合物催化下(E)-α-锡基烯基砜与烯基卤化物的交叉偶联反应,提供了立体选择合成2-芳砜基取代的1,3-二烯的新方法;在Pd(PPh_3)_4/CuI催化下,研究了(E)-α-锡基烯基砜和芳基碘的交叉偶联反应,提供了合成(Z)-1,2-双取代的烯基砜的新方法;研究了(E)-α-锡基烯基砜与炔基溴的偶联反应,提供了立体选择性地合成2-芳砜基取代的1,3-烯炔的新方法;研究了(E)-α-锡基烯基砜与烯丙基溴的偶联反应,提供了立体选择性地合成了2-芳砜基取代的1,4-二烯烃的新方法。
英文短句/例句
1.Study on Copper Catalyzed C-X (N, O, S) Cross-Coupling Reactions铜催化C-X（N，O，S）交叉偶联反应研究
2.Efficient C-S Cross Coupling Catalyzed by Cu_2OCu_2O催化的C-S交叉偶联反应的研究
3.Phosphoramidite-Transition Metal Catalyzed Cross-Coupling Reactions;亚磷酰胺—过渡金属催化的交叉偶联反应的研究
4.Amine-Promoted Transition Metals Palladium-Catalyzed Suzuki-Coupling Reactions;胺促进过渡金属钯催化的Suzuki交叉偶联反应研究
5.Amines as Ligands Promoted Palladium Catalyzed Cross-Coupling Reactions;胺为配体促进钯催化交叉偶联反应的研究
6.The Research of Kumada Cross-Coupling Reaction Catalyzed by Ultrafine Amorphous NiB Alloy;超细NiB非晶合金催化Kumada交叉偶联反应的研究
7.Preparing 2-(naphthalen-2′-yl) thiazole by Pd-Catalyzed Suzuki cross-coupling reactions钯催化Suzuki交叉偶联反应合成2-(2′-萘基)噻唑
8.Palladium/DABCO-Catalyzed Cross-Coupling Reaction and Cerium Salt-Catalyzed Organic Reactions;钯/DABCO催化交叉偶联反应及铈盐催化有机反应的研究
9.Study of the Nickel Complex-Catalyzed Suzuki Cross-Coupling Reaction of Aryl Chlorides and Related Reactions;镍配合物催化氯代芳烃的Suzuki交叉偶联反应及相关反应研究
10.Lewis Acid-Catalyzed Conia-ene Reaction and Transition Metal-Catalyzed Cross-Coupling Reaction路易斯酸催化的Conia-ene环化反应及过渡金属催化的交叉偶联反应
11.Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction and Intramolecular Heck Reaction钯催化Suzuki-Miyaura交叉偶联反应和分子内Heck反应的研究
12.Cross-Coupling Reaction and Its Application in Research of Intramolecular 1, 4-Aromatic Radical Transfer;交叉偶联反应及其在分子内1，4-芳香自由基转移研究中的应用
13.Amines as Ligands in the Copper-Catalyzed Cross-Coupling Reactions;胺作为配体在铜催化下交叉偶联反应中应用研究
14.Palladium-Catalyzed Cross-Coupling Reactions of Compounds Containing N or S Hetero-atom with Aryl Bromides;含N、S杂原子化合物与芳溴的Pd催化交叉偶联反应
15.A Highly Efficient O_2/RuCl_3 System for Catalyzed Cross-Dehydrogenative-Coupling Reactions between Tertiary Amines and Activated C-H BondsO_2/RuCl_3体系催化叔胺与含活性碳氢键化合物的交叉偶联反应研究
16.Bridge Nitrogen Heterocyclic Carbine-Palladium Catalyst Systems Applied in the Cross-Coupling Reactions;桥联氮杂环卡宾—钯催化体系的构建及其在交叉偶联反应中的应用研究
17.The Study to Synthesize α,β-Unsaturated Esters Containing a Trifluoromethyl Group by Suzuki Cross-coupling;Suzuki型交叉偶联反应在合成含三氟甲基的α、β-不饱和酸酯中的应用研究
18.coupled reaction偶联反应，偶合反应
相关短句/例句
cross coupling reaction交叉偶联反应
1.Thecross coupling reaction of unsaturated carbons is one of the most important methods in organic synthesis.对Cu催化交叉偶联反应的最新研究进展作了综述 。
2.Palladium catalyzedcross coupling reaction which is widely used to form C C bond is an important reaction in organic synthesis.钯催化交叉偶联反应是一类用于碳碳键形成的重要反应 ,在有机合成中应用十分广泛。
3)cross-coupling交叉偶联反应
1.Palladium-catalyzed Suzuki-Miyauracross-coupling reaction of organoboron with organic electrophiles has been recognized as one of the most important carbon-carbon bond building reactions.钯催化的有机硼试剂与有机亲电试剂的Suzuki-Miyaura交叉偶联反应是构建碳一碳键的最重要的反应之一。
4)Stille cross-coupling reactionStille交叉偶联反应
1.Recent development of the palladium-catalyzedStille cross-coupling reactions is reviewed, which includes (1) the reactions of organotin compounds with organic electrophilic reagents such as aro-matic halides, alkyl halides, and acyl chlorides etc.综述了钯催化Stille交叉偶联反应的最新研究进展,主要包括三个方面:(1)有机锡化合物与有机亲电试剂如卤代芳香烃、卤代烷烃、酰氯等的反应;(2)Stille反应的机理;(3)Stille反应在有机合成中的应用。
2.This dissertation reported palladium-catalyzed dimerization reaction of terminal alkynes in organic solvents or supercritical carbon dioxide (scCO_2), and palladium-catalyzedStille cross-coupling reaction1.本论文主要研究了在常规有机溶剂和超临界二氧化碳中钯催化末端炔烃的二聚反应及在含氮配体的作用下钯催化Stille交叉偶联反应。
5)Sonogashira cross-coupling reactionSonogashira交叉偶联反应
1.This dissertion mainly describes several organic reactions of alkynes and allenes,including Cu-catalyzedSonogashira cross-coupling reaction,plladium-catalyzed cyclization of N-arylpropiolamides with arynes,and electrophilic cyclization of allenes.Cu_2O/PPh_3/TBAB催化体系高效催化Sonogashira交叉偶联反应。
6)Suzuki cross-coupling reactionSuzuki交叉偶联反应
1.This dissertation mainly described two ligand-free cross-coupling protocols,including ligand-free palladium-catalyzedSuzuki cross-coupling reaction and copper-catalyzed Sonogashira cross-coupling reaction.本论文主要围绕在无配体条件下钯催化的Suzuki交叉偶联反应及铜催化的Sonogashira交叉偶联反应进行了较深入地研究。
2.TheSuzuki cross-coupling reaction is one of the most important methods for the construction of carbon-carbon bonds.Suzuki交叉偶联反应是构建碳-碳键的重要方法之一。
延伸阅读
交叉偶联反应分子式：CAS号：性质：一个有机分子与另一有机分子发生的不对称偶联反应。例如：烯丙基锂与2-氯辛烷可以发生交叉偶联反应生成4-甲基-1-癸烯。格利雅试剂、有机铝、有机锌、有机锡、有机铜、有机铅、有机汞等多种有机金属化合物也都可以与卤化烷等烃基化试剂发生交叉偶联反应，生成相应的不对称烃，是合成不对称烃，特别是单烷基芳烃和含有三级碳原子的链烃的有效方法。交叉偶联反应的范围很广，像芳烃重氮盐与苯酚或N,N-二甲基苯胺的偶联反应，也属于交叉偶联反应。
