Dinuclear ruthenium carbonyls, also known as double-core ruthenium carbonyl compounds, are a class of organometallic compounds containing two ruthenium atoms bridged by carbonyl ligands. These compounds demonstrate unique reactivity and have been of significant interest in the field of synthetic chemistry and catalysis. Their applications range from metal-mediated organic transformations to the development of novel materials and pharmaceuticals. For example, dinuclear ruthenium carbonyls have shown promising catalytic activity in various chemical reactions, such as carbonylation, hydrogenation, and C-C bond formation. Their structural diversity and versatile reactivity make them an intriguing subject of study in the realm of inorganic and organometallic chemistry.
双核钌羰基化合物,dinuclear ruthenium carbonyls
1)dinuclear ruthenium carbonyls双核钌羰基化合物
2)trinuclear ruthenium carbonyl cluster三核钌羰基簇合物
3)unsaturated trinuclear ruthenium carbonyls不饱和三核钌羰基化合物
1.Eight triplet isomers ofunsaturated trinuclear ruthenium carbonyls Ru3(CO)n(n=11,10,9) were predicted using two density functional theory methods combining two ECP basis sets.采用两种密度泛函方法和两种有效核势基组对中性不饱和三核钌羰基化合物Ru3(CO)n(n=11,10,9)的三态异构体进行理论计算,优化出8个稳定异构体。
英文短句/例句
1.Theoretical study of the triplet Ru_3(CO)_n(n=11,10,9) structures三态不饱和三核钌羰基化合物的理论研究
2.A Stereoselective Synthetic Route to (E)- α,β-Unsaturated Thioesters;α,β-不饱和羰基锆化合物的合成及其在高选择合成中的应用
3.Studies on Palladium Catalyzed Carbonylation Reactions of Multifunctional Unsaturated Compounds钯催化下多官能团不饱和化合物的羰基化反应研究
4.Progress in Asymmetric Michael Addition Reaction Between Thiols and α,β-Unsaturated Carbonyl Compounds硫醇与α,β-不饱和羰基化合物的不对称Michael加成反应的研究进展
5.Studies on Ni Catalyzed Conjugate Addition of Organoboronic Acids to α, β-unsaturated Carbonyl Compounds;镍催化的有机硼酸与α，β-不饱和羰基化合物的共轭加成反应研究
6.Study on Selective Reduction of Carbon-Carbon Double Bond of α, β-Unsaturated Carbonyl Compounds;α，β-不饱和羰基化合物的碳碳双键选择性还原研究
7.Progress in Michael Addition Reaction between Thiols and α,β-unsaturated Carbonyl Compounds;硫醇与α,β-不饱和羰基化合物的Michael加成反应的研究进展
8.Research in the Synthesis of α-Halo-α, β-Unsaturated Esters and O-H Insertion of α-Diazo Carbonyl Compounds;α-卤代-α，β-不饱和酯的合成与α-重氮羰基化合物O-H插入反应的研究
9.Synthesis and electrochemical behavior of α,β-unsaturated carbonyl compounds bearing propyl-bridged biferrocenyl substituents含丙基桥联双二茂铁的α,β-不饱和羰基衍生物的合成及电化学性质
10.Syntheses of New Biferrocene Derivatives Containing a α,β-Unsaturated Carbonyl Bridge and Their Langmuir Monolayers新型α，β－不饱和羰基桥联双二茂铁衍生物的合成及其成膜性
11.Hydrogenation of Unsaturated Compounds over Ruthenium Based Catalysts in Aqueous Media;水体系中钌催化不饱和有机物加氢反应研究
12.Syntheses and Characterizations of Ru-phosphine-diamine Complexes and Applications in Catalytic Hydrogenations of Carbonyl Compounds;钌膦二胺配合物中膦配体的电子效应对羰基催化加氢的影响研究
13.Synthesis and Characterization of Rhenium Tricarbonyl Core Complexes of Bile Acid Derivatives胆汁酸衍生物三羰基铼核配合物的合成与表征
14.The Study on Structure of Copolymer Rhodium Complexes and Their Catalytic Properties for Methanol Carbonylation and Copolymer Ruthenium Complex in Hydrogenation;共聚物铑配合物结构与催化甲醇羰基化反应的性能及其钌配合物催化加氢研究
15.Theoretical study on mononuclear and binuclear cobalt carbonyl nitrosyls单核和双核钴羰基-亚硝基配合物的理论研究
16.Asymmetric Reduction of Carbonyl Compounds Containing Amino Group;含有氨基的羰基化合物的不对称还原
17.Studies on Influenes of Diamine Structures in Ru-phosphine-diamine Complexes on Selective Hydrogenation of Unsaturated Carbonyl Compounds;钌膦二胺配合物中二胺结构的变化对羰基催化加氢性能的影响研究
18.Studies on Synthesis of Hydantoin Derivatives and Carbonylation Reaction Using Triphosgene;乙内酰脲衍生物的合成和三光气在羰基化环合反应中的研究
相关短句/例句
trinuclear ruthenium carbonyl cluster三核钌羰基簇合物
3)unsaturated trinuclear ruthenium carbonyls不饱和三核钌羰基化合物
1.Eight triplet isomers ofunsaturated trinuclear ruthenium carbonyls Ru3(CO)n(n=11,10,9) were predicted using two density functional theory methods combining two ECP basis sets.采用两种密度泛函方法和两种有效核势基组对中性不饱和三核钌羰基化合物Ru3(CO)n(n=11,10,9)的三态异构体进行理论计算,优化出8个稳定异构体。
4)carbonyl ruthenium complex羰基钌配合物
5)ruthenium carbonyl cluster钌羰基簇合物
1.The reaction of Ru3(CO)12 with five membered cyclic SP(S)(Fc)N(Ph)NC(Me) gave two novel trinuclear and tetranuclearruthenium carbonyl clusters containing capping S atoms in Ru3(CO)8(μ 3 S)2[P(Fc)N(Ph)NC(Me)S] 1 and Ru4(CO)7(μ CO)3(μ 4 S)2[P(Fc)N(Ph)NC(Me)S] 2 (Fc=C5H5FeC5H4).近年来,我们合成了一系列含硫、磷桥基的铁、钴、钌羰基簇合物。
6)β dicarbonyl compound双羰基化合物
延伸阅读
二氯三羰基钌多聚物分子式：[Ru(CO)3Cl2]nCAS号：性质：黄色粉末。很稳定,几乎不溶于大多数有机溶剂。加热回流水合三氯化钌、盐酸和甲酸的混合物,在氮气保护下蒸发至干,120℃下干燥而得。作试剂。
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